Everything about Optical Activity totally explained
Optical rotation or
optical activity is the rotation of
linearly polarized light as it travels through certain materials. It occurs in solutions of
chiral molecules such as
sucrose (sugar), solids with rotated
crystal planes such as
quartz, and
spin-polarized gases of atoms or molecules. It is used in the
sugar industry to measure syrup concentration, in
optics to manipulate
polarization, in
chemistry to characterize substances in solution, and is being developed as a method to measure
blood sugar concentration in
diabetic people.
History
The rotation of the orientation of linearly polarized light was first observed in 1811 in
quartz by French physicist
François Jean Dominique Arago. Around this same time,
Jean Baptiste Biot also observed the effect in liquids and gases of organic substances such as
turpentine. In 1822, the English astronomer Sir Joun F.W. Herschel discovered that different crystal forms of quartz rotated the linear polarization in different directions. Simple
polarimeters have been used since this time to measure the concentrations of simple sugars, such as
glucose, in solution. In fact, one name for glucose, dextrose, refers to the fact that it causes linearly polarized light to rotate to the right or side. Similarly, levulose, more commonly known as
fructose, causes the plane of polarization to rotate to the left. Fructose is even more strongly levorotatory than glucose is dextrorotatory. Invert sugar, formed by adding fructose to a solution of glucose, gets its name from the fact that the conversion causes the direction of rotation to "invert" from right to left.
In 1849,
Louis Pasteur resolved a problem concerning the nature of
tartaric acid. A solution of this compound derived from living things (specifically,
wine lees) rotated the plane of
polarization of light passing through it, but tartaric acid derived by
chemical synthesis had no such effect, even though its reactions were identical and its elemental composition was the same. Pasteur noticed that the crystals came in two asymmetric forms that were mirror images of one another. Sorting the crystals by hand gave two forms of the compound: solutions of one form rotated polarized light clockwise, while the other form rotated light counterclockwise. An equal mix of the two had no polarizing effect on light. Pasteur deduced the molecule in question was asymmetric and could exist in two different forms that resemble one another as would left- and right-hand gloves, and that the organic form of the compound consisted purely of the one type.
In 1874,
Jacobus Henricus van 't Hoff and
Joseph Achille Le Bel independently proposed that the phenomenon of optical activity could be explained by assuming that the chemical bonds between carbon atoms and their neighbors were directed towards the corners of a regular tetrahedron. This led to a better understanding of the three-dimensional nature of molecules.
Theory
Optical activity is a type of
birefringence. Any linear polarization of light can be written as an equal combination of right-hand (RHC) and left-hand circularly (LHC) polarized light:
» ,
where
is the wavelength of the light (in vacuum). Consequently, the final polarization is rotated to angle
.
Generally, the refractive index depends on the wavelength (see
dispersion). The variation in rotation with the wavelength of the light is called
optical rotatory dispersion (ORD). ORD spectra and
circular dichroism spectra are related through the
Kramers-Kronig relations. Complete knowledge of one spectrum allows the calculation of the other.
In summary, the degree of rotation depends on the color of the light (the yellow sodium D line near 589 nm
wavelength is commonly used for measurements), the path length
and the properties of the material (for example
or
specific rotation and concentration).
Areas of use
For a pure substance in solution, if the color and path length are fixed and the specific rotation is known, the observed rotation can be used to calculate the concentration. This usage makes a polarimeter a tool of great importance to those who trade in or use sugar syrups in bulk.
In the presence of
magnetic fields all molecules have optical activity. A magnetic field aligned in the direction of light propagating through a material will cause the rotation of the plane of linear polarization. This
Faraday effect is one of the first discoveries of the relationship between light and electromagnetic effects.
Optical activity or rotation shouldn't be confused with circularly polarized light. Circularly polarized light is often presented as a linear polarization rotating as the light propagates. However, in this picture the polarization completely rotates in a length equal to the wavelength (roughly one micrometre) and it can happen in vacuum. In contrast, optical activity only occurs in a material and a complete rotation occurs in a length of millimeters to meters, depending on the material.
Further Information
Get more info on 'Optical Activity'.
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